{"id":114,"date":"2017-10-10T10:58:00","date_gmt":"2017-10-10T02:58:00","guid":{"rendered":"http:\/\/www.126dmea.com\/?p=114"},"modified":"2017-10-10T10:58:12","modified_gmt":"2017-10-10T02:58:12","slug":"3s6s-ji3s6r-3-bianyangjiaji-6-jiaji-malin-25-ertongdezhibei","status":"publish","type":"post","link":"https:\/\/sienw.com\/index.php\/archives\/114","title":{"rendered":"(3S,6S)-\u53ca(3S,6R)-3-\u82c4\u6c27\u7532\u57fa-6-\u7532\u57fa-\u5417\u5549-2,5-\u4e8c\u916e\u7684\u5236\u5907"},"content":{"rendered":"<p>\u4ee52-\u6eb4\u4e19\u9178\u548c N-\u53d4\u4e01\u6c27\u7fb0\u57fa-O-\u82c4\u57fa-L-\u4e1d\u6c28\u9178\u4e3a\u8d77\u59cb\u8bd5\u5242\u9996\u5148\u5236\u5f97 N-\uff082-\u6eb4\u4e19\u57fa\uff09-O-\u82c4\u57fa-L-\u4e1d\u6c28\u9178\uff08BPBS\uff09\uff0c\u5728N,N-\u4e8c\u7532\u57fa\u7532\u9170\u80fa\uff08DMF\uff09\/\u4e09\u4e59\u80faN\uff09\u6eb6\u5242\u4e2d 80 \u2103\u7ecf9 h \u540eBPBS\u53d1\u751f\u5206\u5b50\u5185\u73af\u5316\u53cd\u5e94\u751f\u6210\uff083S,6S\uff09-3-\u82c4\u6c27\u7532\u57fa-6-\u7532\u57fa-<a href=\"http:\/\/www.126dmea.com\/\">\u5417\u5549-<\/a>2,5-\u4e8c\u916e[\uff083S,6S\uff09-BMMD]\u53ca\uff083S,6R\uff09-BMMD \u5171\u5b58\u4f53\uff0c\u4ea7\u738770%\u3002<\/p>\n<p>\u5c06\u6240\u5236\u5f97\u7684\u5171\u5b58\u4f53\u4ee5\u4e59\u9178\u4e59\u916f\u4e3a\u91cd\u7ed3\u6676\u6eb6\u5242\u91c7\u7528\u5fae\u5206\u91cd\u7ed3\u6676\u6cd5\uff0c\u7ecf 4 \u6b21\u201c\u6eb6\u89e3-\u90e8\u5206\u91cd\u7ed3\u6676\u201d\u64cd\u4f5c\u5faa\u73af\u5236\u5f97\u4e24\u79cd\u7eaf\u5149\u5b66\u6784\u578b\u7684\uff083S,6S\uff09-BMMD \u548c\uff083S,6R\uff09-BMMD\u3002\u5c06\u4e24\u79cd\u5149\u5b66\u7eaf\u53cc\u624b\u6027\u4e2d\u5fc3\u7684 BMMD \u5206\u522b\u6eb6\u4e8e\u4e59\u9178\u4e59\u916f\uff0c\u5ba4\u6e29\u4e0b\u57f9\u517b\u5f97\uff083S,6S\uff09-BMMD \u548c\uff083S,6R\uff09-BMMD \u7684\u5355\u6676\u4f53\uff0c\u4ee5\u5c04\u7ebf\u884d\u5c04\u6cd5\u6d4b\u5b9a\u4e0a\u8ff0\u4e24\u79cdBMMD\u7684\u5206\u5b50\u7ed3\u6784\u3002<\/p>\n<p>\u5b9e\u9a8c\u90e8\u5206\u8bd5\u5242\u4e0e\u4eea\u5668\uff1aN-Boc-O-Bzl-L-\u4e1d\u6c28\u9178\uff0899%\uff09\u4e3a\u6210\u90fd\u4e09\u9ad8\u751f\u5316\u6709\u9650\u516c\u53f8\u4ea7\u54c1\uff0c2-\u6eb4\u4ee3\u4e19\u9178\uff08AR\uff09\u4e3a\u5929\u6d25\u6d25\u534e\u6c38\u80dc\u6709\u9650\u516c\u53f8\u4ea7\u54c1\u3002\u4e59\u9178\u4e59\u916f\u3001\u4e09\u4e59\u80fa\u30011,4-\u4e8c\u6c27\u516d\u73af\u5747\u4e3a\u5206\u6790\u7eaf\u8bd5\u5242\u7528\u524d\u7ecf\u5e72\u71e5\u5242\u5904\u7406\u540e\u91cd\u84b8\u3002<\/p>\n<p>\u745e\u58ebBRUCKER 400 MHz\u6838\u78c1\u5171\u632f\u8c31\u4eea\uff1b\u7f8e\u56fdThermofinnigan\u516c\u53f8\u578b\u8d28\u8c31\u4eea\uff1b\u5fb7\u56fd Analysensysteme Gmbl\u516c\u53f8\u578b\u5143\u7d20\u5206\u6790\u4eea\uff1b\u5355\u6676\u7ed3\u6784\u6d4b\u8bd5\u91c7\u7528CCD \u9762\u63a2\u884d\u5c04\u4eea\uff0c\u91c7\u7528\u7ecf\u77f3\u58a8\u5355\u8272\u5668\u5355\u8272\u5316\u7684Mo K\u03b1\u5c04\u7ebf\u4ee5\u03c6\uff0c\u03c9 \u626b\u63cf\u65b9\u5f0f\u6536\u96c6\u72ec\u7acb\u884d\u5c04\u70b9\u3002<\/p>\n<p>\u5438\u6536\u6821\u6b63\u91c7\u7528SADABS \u7a0b\u5e8f\uff0c\u6676\u4f53\u7ed3\u6784\u7531\u76f4\u63a5\u6cd5\uff08SHELXS-97\uff09\u89e3\u51fa\u5e76\u5bf9\u5176\u8fdb\u884c\u5168\u77e9\u9635\u5c0f\u4e8c\u4e58\u6cd5\u4fee\u6b63\u540e\u5373\u5f97\u5230\u7ed3\u679c\u3002\u5168\u90e8\u8ba1\u7b97\u7528 Bruker Saint \u7a0b\u5e8f\u5b8c\u6210\u3002<\/p>\n","raw":"","protected":false},"excerpt":{"rendered":"<p>\u4ee52-\u6eb4\u4e19\u9178\u548c N-\u53d4\u4e01\u6c27\u7fb0\u57fa-O-\u82c4\u57fa-L-\u4e1d\u6c28\u9178\u4e3a\u8d77\u59cb\u8bd5\u5242\u9996\u5148\u5236\u5f97 N-\uff082-\u6eb4\u4e19\u57fa\uff09-O-\u82c4\u57fa-L-\u4e1d\u6c28\u9178\uff08BPBS\uff09\uff0c\u5728N,N-\u4e8c\u7532\u57fa\u7532\u9170\u80fa\uff08DMF\uff09\/\u4e09\u4e59\u80faN\uff09\u6eb6\u5242\u4e2d 80 \u2103\u7ecf9 h \u540eBPBS\u53d1\u751f\u5206\u5b50\u5185\u73af\u5316\u53cd\u5e94\u751f\u6210\uff083S,6S\uff09-3-\u82c4\u6c27\u7532\u57fa-6-\u7532\u57fa-\u5417\u5549-2,5-\u4e8c\u916e[\uff083S,6S\uff09-BMMD]\u53ca\uff083 &#8230;<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":[],"categories":[3],"tags":[],"post_thumbnail_image":"","content_first_image":"","post_medium_image_300":"","post_thumbnail_image_624":"","post_frist_image":"","post_medium_image":"","post_large_image":"","post_full_image":"","post_all_images":[],"videoAdId":"","listAd":"0","listAdId":"","listAdEvery":5,"total_comments":0,"category_name":"\u4ea7\u54c1\u65b0\u95fb","post_date":"2017-10-10","like_count":"0","praiseWord":"\u9f13\u52b1","copyright_state":"","excitationAd":"0","rewardedVideoAdId":"","detailAdId":"","detailAd":"0","enterpriseMinapp":"0","audios":[],"postImageUrl":"https:\/\/sienw.com\/wp-content\/uploads\/2023\/10\/1-9.jpg","avatarurls":[],"related_posts":null,"pageviews":41,"next_post_id":117,"next_post_title":"\u4e8c\u7532\u57fa\u4e59\u9187\u80fa\u6cc4\u9732\u8be5\u5982\u4f55\u5904\u7406","previous_post_id":112,"previous_post_title":"Synthesis and Crystal Structures of Chiral","_links":{"self":[{"href":"https:\/\/sienw.com\/index.php\/wp-json\/wp\/v2\/posts\/114"}],"collection":[{"href":"https:\/\/sienw.com\/index.php\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/sienw.com\/index.php\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/sienw.com\/index.php\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/sienw.com\/index.php\/wp-json\/wp\/v2\/comments?post=114"}],"version-history":[{"count":1,"href":"https:\/\/sienw.com\/index.php\/wp-json\/wp\/v2\/posts\/114\/revisions"}],"predecessor-version":[{"id":115,"href":"https:\/\/sienw.com\/index.php\/wp-json\/wp\/v2\/posts\/114\/revisions\/115"}],"wp:attachment":[{"href":"https:\/\/sienw.com\/index.php\/wp-json\/wp\/v2\/media?parent=114"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/sienw.com\/index.php\/wp-json\/wp\/v2\/categories?post=114"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/sienw.com\/index.php\/wp-json\/wp\/v2\/tags?post=114"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}