化工用碳酸鈣制取丙酸鈣方法
丙(bing)酸(suan)(suan)(suan)(suan)(suan)鈣為白色結(jie)晶顆粒或(huo)結(jie)晶性(xing)粉末。無臭或(huo)略(lve)帶(dai)丙(bing)酸(suan)(suan)(suan)(suan)(suan)氣味,有(you)吸濕性(xing),易溶于(yu)(yu)水,不(bu)溶于(yu)(yu)醇類。丙(bing)酸(suan)(suan)(suan)(suan)(suan)鈣為較新的食品防霉劑,是(shi)酸(suan)(suan)(suan)(suan)(suan)性(xing)防霉劑丙(bing)酸(suan)(suan)(suan)(suan)(suan)的鈣鹽,在(zai)(zai)酸(suan)(suan)(suan)(suan)(suan)性(xing)條件下,產生游離(li)丙(bing)酸(suan)(suan)(suan)(suan)(suan),比山梨酸(suan)(suan)(suan)(suan)(suan)弱,比醋酸(suan)(suan)(suan)(suan)(suan)強,具有(you)抗菌(jun)作用,對黑曲霉、嗜氣性(xing)芽孢桿菌(jun)有(you)抑(yi)制作用。丙(bing)酸(suan)(suan)(suan)(suan)(suan)鈣由丙(bing)酸(suan)(suan)(suan)(suan)(suan)和氫(qing)(qing)氧化(hua)(hua)鈣或(huo)碳酸(suan)(suan)(suan)(suan)(suan)鈣反應制得(de)。工(gong)業一般用氫(qing)(qing)氧化(hua)(hua)鈣為原(yuan)料,在(zai)(zai)反應鍋中調氫(qing)(qing)氧化(hua)(hua)鈣成(cheng)(cheng)懸濁液,加(jia)入丙(bing)酸(suan)(suan)(suan)(suan)(suan)反應,終點pH7~8,經過濾干燥得(de)成(cheng)(cheng)品。
用碳酸鈣制取丙酸鈣方法如下:
首先將原料碳酸鈣制(zhi)(zhi)成(cheng)水懸濁(zhuo)液,所用水要(yao)經(jing)過(guo)(guo)精制(zhi)(zhi)凈化除去(qu)重金屬(shu)鎂等雜質。將CaCO3水懸濁(zhuo)液定(ding)量(liang)(liang)投入(ru)中(zhong)(zhong)(zhong)和(he)反(fan)應(ying)(ying)釜(fu)(fu)內,保(bao)持釜(fu)(fu)內溫(wen)度60~80℃,邊(bian)攪拌邊(bian)加入(ru)丙(bing)酸,中(zhong)(zhong)(zhong)和(he)反(fan)應(ying)(ying)歷時(shi)2~3小時(shi),此時(shi)有(you)大量(liang)(liang)的(de)(de)CO2氣體(ti)(ti)逸(yi)出(chu)(chu),可(ke)經(jing)過(guo)(guo)冷凝(ning)器的(de)(de)放空管(guan)排出(chu)(chu)。通過(guo)(guo)調節(jie)外加熱(re)溫(wen)度、加酸及攪拌速度使(shi)反(fan)應(ying)(ying)達到佳條件,反(fan)應(ying)(ying)終(zhong)(zhong)點pH值應(ying)(ying)控制(zhi)(zhi)在7~8,此反(fan)應(ying)(ying)為可(ke)逆反(fan)應(ying)(ying),應(ying)(ying)及時(shi)將CO2氣體(ti)(ti)排出(chu)(chu)才可(ke)更(geng)好地(di)控制(zhi)(zhi)反(fan)應(ying)(ying)的(de)(de)終(zhong)(zhong)點。將中(zhong)(zhong)(zhong)和(he)后(hou)的(de)(de)水溶液經(jing)過(guo)(guo)真(zhen)空過(guo)(guo)濾,所得濾液在蒸發釜(fu)(fu)中(zhong)(zhong)(zhong)濃縮,然后(hou)放入(ru)結晶槽中(zhong)(zhong)(zhong)在常溫(wen)常壓下緩慢冷卻結晶。母液可(ke)返回蒸發釜(fu)(fu)中(zhong)(zhong)(zhong)套用2~3次后(hou)棄(qi)去(qu)。分離出(chu)(chu)的(de)(de)固(gu)體(ti)(ti)烘干成(cheng)小顆粒(li)經(jing)粉碎、計量(liang)(liang)、包裝即得丙(bing)酸鈣成(cheng)品。
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